Monitoring and Reporting VOCs in Ambient Air

Volatile organic compounds (VOCs) are part of the large hydrocarbon family, a vast array of aliphatic, aromatic hydrocarbons, their halogenated derivatives, alcohols, ketones and aldehydes. VOCs have a property of conversion into vapour or gas without any chemical change. They are highly reactive hydrocarbons and participate in atmospheric photochemical reactions. Some of them have negligible photochemical activity; however they play an important role as heat trapping gases in atmosphere. VOC of both primary and secondary origin in ambient air have immense importance as they have direct as well as indirect effects on climate change, ecology and human health. Many VOCs are of natural origin while many owe their existence to anthropogenic activities. Natural sources of VOCs include forests, termites, oceans, wetlands, Tundras and volcanoes. Estimated global emission rate of biogenic VOCs is 1150 Tg yr-1 (Guenther et. al., 1995). The anthropogenic sources of VOCs consist of vehicular emissions, petroleum products, chemicals, manufacturing industries, painting operations, varnishes, coating operations, consumer products, petroleum handling, auto refinishing, cold clean degreasing, printing inks, dry-cleaning etc. In presence of oxides of nitrogen and sunlight, VOCs form ozone and other products. Oxidation of VOCs by reaction with hydroxyl radicals is the main removal process. The oxidation of complex organic molecules leads to the fragmentation, production of a range of reactive free radicals and more stable smaller molecules such as aldehydes. VOCs are cause of concern firstly due to its role in formation of ground level ozone and smog and secondly due to some of them being carcinogenic, mutagenic and teratogenic in nature. Adverse effects of ozone on human health, crop viability and yields are well documented. Wide range of VOCs, imply wide range of reaction rates, which means large range of transport distances. Many VOCs have low reactivity and thus long atmospheric life times and can be classified as Persistent Organic Pollutants (POPs). Some VOCs are Hazardous Air Pollutants (HAPs) by virtue of their toxicity. International concerns regarding VOCs arise due to their ability of long range transport, distribution and accumulation in various components of environment, their toxic nature and significant contribution from natural sources. Ambient air monitoring of VOC is aimed to control or avoid adverse impacts on humans and ecology. This should also result in knowledge of types and category of VOCs in terms of photochemical ozone creating potential of VOCs, concentrations of VOC species, their dispersion routes and fate in